Authors : Ndema Mbongué Jean Lavenir, Emmanuel Eseya Mengu Junior, Mboudou Germain Marie Monesperance
Volume/Issue : Volume 5 - 2020, Issue 1 - January
Google Scholar : https://goo.gl/DF9R4u
Scribd : https://bit.ly/2tweRez
The Loum area is located in the
southwestern part of the central domain of the Pan-
African Fold Belt in Cameroon. The assessment of
vanadium in this area is carried out through stream
sediments survey in River Mbete. Collected samples
were analyzed by AR-ICP-MS method. Analyses show
Fe2O3 and MgO enrichment and mostly negative trend
of major oxides with vanadium. V (av. = 926.7 ppm) and
Mn (av. = 613.8 ppm) are highly concentrated in stream
sediments while Ba, Ga and Sr have low contents, and
the presence of Ba and Sr suggests their association with
feldspar. Histogramic distributions show that trace
elements are positively skewed. Strongly positive
correlation coefficients and the close association
between V and some elements indicates a common
source. The antithetic relationship between vanadium
and Co, Cr, Mn, Ni implies an empirical inverse
distribution of Co, Cr, Mn, Ni, V in the V-formation.
The correlation of Zn with Co, Cr, Mo, Mn, Ni, V, Sc is
a reflection of their transition metals relationship, while
the presence of Th and La reflects their mutual
association as light ion Lithophile elements. Trace
element concentrations were of geogenic origins and the
high vanadium contents in the concentrates could be
link to the volcanic emission. A four-factor model
cumulatively accounting for 85.488% of the total
variance data is recorded: factor 1 (Co- Cr- Mn- Ni- Sc)
accounts for 43.516% of the total variance. The high
loading of trace elements in factor 1 suggests their high
mobility within the environment and the 43.516% of
total variance suggests the significance of the elements
in stream sediments, and Ni is associated with V. Factor
2 (Cr- Mn- zn- Ti) represents 18.496% of total variance
and reflects an environment for the enrichment of Cr
and Mn association. Factor 3 (Ba- Sc- Sr) accounts for
16.044% reflecting a lithological controlled formation.
Factor 4 (Hg- Pb) contributes about 7.432% and
suggests their association with chalcophile elements.
Principal component analysis results in four
components that explain 85.488% of the total variance.
The first component (Co, Cr, Cu, Mn, Ni, Sc, Zn)
accounts for 53.882% of the variance is highly
correlated and reflects the association of V with
transition metals. The second component (Cu, Pb, Sb)
accounting for 16.180% is correlated with chalcophile
elements. The third component accounting for 8.612%
of the variance is very weakly loaded. The fourth
component (Pb, Hg) accounting for 6.814%. The
resulting component plot shows the placement of
elements in three major principal components, in which
elements scattering in the rotated space displaying their
mutual association. Cluster analysis gave rise to four
clusters: cluster 1 (Ba, Ga, Th, Co, La) exhibits a strong
correlation between Ba and Ga. Cluster 2 (Cr, Zn, Pb,
Cu, Ni) shows a clear close geochemical relationship
between the elements in this group. Cluster 3 (Mo, Sc,
Sr) displays a strong correlation between Mo and Sc.
Cluster 4 (Mn, V, Hg, Sb) illustrates a close association
between Mn and V. The majority of trace elements fall
within the background values, except Mn, Ni, Pb, V that
contents exceed the upper background threshold values
and therefore refer to anomalous, but these anomalous
elements are not viable enough to be exploited. The
median value of Loum vanadium is higher than the
median values of vanadium recorded in Fongo-Tongo
(Cameroon), in the world: Canada, Foregs samples,
Upper continental crust, soil, and smaller than the one
obtained in Ngaoundal (Cameroon). In the boxplot,
patterns in V distribution between all solid sample
media and laterite are broadly similar and different to
the one reported from Loum V that shows higher. The
results of this work serve as guide for vanadium
exploration in the Loum area.
Keywords : Loum Area; Pan-African Fold Belt; Vanadium; River Mbete; V-Formation; Geogenic Origins; Upper Background Threshold.