The present research work aimed to study the
synthesis of isoamyl acetate from isoamyl alcohol, using
the Fischer esterification method that was based on the
formation of an ester by refluxing a carboxylic acid and
an alcohol, for this purpose. 5.3 mL of isoamyl alcohol
and 7.3 mL acetic acid were used, which were mixed in a
round bottom flask and then 1.2 mL of sulfuric acid was
added while the flask was shaken, in addition these tests
allowed to identify that They are highly exothermic
reactions due to the evolution of heat. The reflux
condenser was then coupled with lightly greased tips and
boiled on the hot plate, keeping the reflux for a time of
one hour. At the end of this time, it was allowed to cool to
room temperature and all the liquid was transferred to a
separatory funnel with 10 mL of ice water. It was gently
stirred, and decanted separating the lower aqueous
layer. Subsequently the resulting organic layer was
washed with sodium bicarbonate, to remove excess acetic
acid. In this extraction process, there was release of CO2,
which caused an overpressure inside the funnel.
Subsequently, the extract was verified with pH indicator
paper to determine the basicity of the organic layer with
pH 8. Subsequently, the organic phase was dried with
anhydrous sodium sulfate followed by a decantation and
a distillation that allowed us to obtain a colorless liquid
with a strong characteristic smell of banana. Finally, the
amount of isoamyl acetate obtained in the reaction was
determined, which was 4.2 mL and the reaction yield
calculations were made, which gave a percentage of
58.09%, which is very acceptable.
Keywords : Esterification, Artificial Flavors, Isoamyl Acetat